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论文类型：期刊论文

发表时间：2010-01-15

发表刊物：International Symposium on Catalysis

收录刊物：SCIE、EI、CPCI-S

卷号：149

期号：1-2

页面范围：11-18

ISSN号：0920-5861

关键字：Molybdenum phosphide; TiO2; Hydrodenitrogenation; Quinoline; Decahydroquinoline; Promoter

摘要：The effect of TiO2 Oil the hydrodenitrogenation (HDN) performance of MoP/MCM-41 was investigated using quinoline and decahydroquinoline as the model molecules. The catalysts were characterized by XRD, CO chemisorption, TEM. TPR and pyridine FT-IR. Addition of TiO2 enhanced the C-N bond cleavage activity of MoP/MCM-41 but inhibited its dehydrogenation activity. A maximum HDN activity was observed when the TiO2 loading was 5 wt% The characterization results indicated that introduction of TiO2 did not affect the formation of Mol? phase The TiO2-containing catalysts possessed higher CO uptake than MoP/MCM-41, but no significant differences in the acid properties and particle size distributions were observed for all the catalysts. XPS results revealed a Surface enrichment of TiO2 Ti-containing catalysts and small amount of these surface TiO2 can be partially reduced to Tin+ (n < 4) It is suggested that these Tin+ (n < 4) species may be responsible for the promoting effect of TiO2 on the HDN performance of MoP/MCM-41 (C) 2009 Elsevier B.V. All rights reserved.