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论文类型：期刊论文

发表时间：2018-06-01

发表刊物：CATALYSIS LETTERS

收录刊物：SCIE

卷号：148

期号：6

页面范围：1579-1588

ISSN号：1011-372X

关键字：Ni2P; Nickel phosphosulfide phase; Quinoline; Decahydroquinoline; Hydrodenitrogenation; Hydrogenation; C-N bond cleavage

摘要：The hydrodenitrogenation (HDN) of quinolone (Q) and decahydroquinoline (DHQ) over a Ni2P catalyst prepared by the reduction of a conventional phosphate precursor and a surface nickel phosphosulfide phase (Ni2P-S) obtained by the reduction of Ni2P2S6 were studied. A reaction network of the HDN of Q over Ni2P was proposed. Both the hydrogenation and C-N bond cleavage activities of Ni2P were enhanced after the introduction of sulfur. The surface sulfur species of Ni2P-S changed significantly after the HDN of DHQ. The thiolate or thiol species were detected as the major sulfur-containing species in the surface of the spent Ni2P-S catalyst.
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