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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：工业催化
办公地点：西部校区化工实验楼B321
联系方式：大连市高新区凌工路2号大连理工大学西部校区B321
电子邮箱：ajwang@dlut.edu.cn
Catalytic performance of P-modified MoO3/SiO2 in oxidative desulfurization by cumene hydroperoxide
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论文类型：期刊论文
发表时间：2013-12-05
发表刊物：CATALYSIS COMMUNICATIONS
收录刊物：SCIE、EI、Scopus
卷号：42
页面范围：6-9
ISSN号：1566-7367
关键字：Oxidative desulfurization; Supported Mo-P oxides; Dibenzothiophene; Diesel
摘要：Phosphorous-modified MoO3/SiO2 catalysts with various P/Mo molar ratios (MoPxO/SiO2, x = 0.3 - 3.0) were prepared by co-impregnation and compared with MoO3/SiO2 in the oxidation of dibenzothiophene by cumene hydroperoxide. The addition of P significantly enhanced the catalytic performance, and MoP1.0O/SiO2 exhibited the highest oxidation activity. XRD characterization indicated that the active phase of MoP1.0O/SiO2 was amorphous, whereas P-31-NMR measurements revealed that MoP1.0O/SiO2 had a similar connectivity of Mo-O-P to H3PMo12O40. The total sulfur of a hydrotreated diesel was reduced from 298 to 5 ppmw by oxidation with CHP and subsequent dimethylformamide extraction. (C) 2013 Elsevier B.V. All rights reserved.