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Plasma driven ammonia decomposition on a Fe-catalyst: eliminating surface nitrogen poisoning
Indexed by:期刊论文
Date of Publication:2013-05-08
Journal:CHEMICAL COMMUNICATIONS
Included Journals:SCIE、PubMed、Scopus
Volume:49
Issue:36
Page Number:3787-3789
ISSN No.:1359-7345
Abstract:Strongly adsorbed N atoms inhibit the ammonia decomposition reaction rate. Plasma-driven catalysis can solve this problem and increase the ammonia conversion from 7.8% to 99.9%. (NH3)-N-15 isotope tracing and optical emission spectroscopy show that gas-phase active species (NH3*, NH center dot) in the plasma zone facilitate the desorption step by an Eley-Rideal (E-R) interaction.