Indexed by:期刊论文

Date of Publication:2009-12-10

Journal:JOURNAL OF CATALYSIS

Included Journals:SCIE、EI、Scopus

Volume:268

Issue:2

Page Number:376-383

ISSN No.:0021-9517

Key Words:Liquid-phase reaction; Cascade acylation/dehydration; Micro-/nano-sized H-beta zeolites; Heterogeneous catalysis; 2-Methylanthraquinone; One-pot synthesis

Abstract:Liquid-phase cascade acylation/dehydration reactions over various zeolite catalysts were performed to synthesize 2-methylanthraquinone (2-MAQ). Many characterization techniques such as NH3-TPD pyridine-IR BET, XRD, SEM, TEM, XRF, and TGA have been employed to study the relationship between the catalytic behavior and the nature of catalysts. The present work provides evidence that the acidity, pore size, particle size, and surface area of zeolites strongly affect both the catalytic properties and the coke formation. Moreover, it is discovered that the reaction activity of phthalic acid (PA) is higher than that of phthalic anhydride, and the yield of 2-MAQ reached 82.2% when PA was used. which opened a new avenue for one-pot synthesizing 2-MAQ by using PA as an acylation reagent. The catalyst can be recycled four times only with a slight decrease in activity. The nano-sized H-beta zeolite could be a promising liquid-phase cascade acylation/dehydration catalyst for clean one-pot synthesis of 2-MAQ. (c) 2009 Elsevier Inc. All rights reserved.