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论文类型：期刊论文

发表时间：2010-12-01

发表刊物：CHEMICAL ENGINEERING JOURNAL

收录刊物：SCIE、EI、Scopus

卷号：165

期号：2

页面范围：709-713

ISSN号：1385-8947

关键字：Palladium nanoparticles; Microemulsion; Hydrogenation; o-Chloronitrobenzene

摘要：The formation and catalytic properties of well-dispersed palladium (Pd) nanoparticles in water-in-oil (w/o) microemulsions containing octadecyl amine polyoxyethylene ether (OAPE-5) and hydrogenated tallow amine (HTA) have been investigated. The size and structure of the nanoparticles were characterized by TEM and XRD analyses and the effects of microemulsion composition on particle sizes were assessed using FTIR spectroscopy. The results of TEM and XRD indicated that the particles were of a face centered cubic structure form and their mean diameter was 10 nm. Results of FTIR analysis indicated strong interactions between Pd nanoparticles and surfactant molecules. Use of these Pd nanoparticles for the hydrogenation of o-chloronitrobenzene in the presence of alkali produced a 3:1 ratio of aniline to o-chloroaniline and none of the frequently observed nitrobenzene or 2.2'-dichlorohydrazoebenzene. (C) 2010 Elsevier B.V. All rights reserved.