|
个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：精细化工. 高分子材料
办公地点：西部校区化工实验楼A座204室
电子邮箱：shen_kh@dlut.edu.cn
Hydrogenation of o-chloronitrobenzene on a Pd/C catalyst doped with metal oxide nanoparticles
点击次数：
论文类型：期刊论文
发表时间：2008-07-15
发表刊物：CHEMICAL ENGINEERING JOURNAL
收录刊物：SCIE、EI
卷号：141
期号：1-3
页面范围：368-374
ISSN号：1385-8947
关键字：Pd/C catalyst; nanoparticles; 2,2 '-dichlorohydrazobenzene; hydrogenation
摘要：Pd/C catalysts doped with cerium oxide and iron oxide nanoparticles were prepared by thermal decarboxylation in the presence of cetylsulfonyl acetate, and used in the hydrogenation of o-chloronitrobenzene to give high yields of 2,2'-dichlorohydrazobenzene. It was found that the stability and activity of the Pd/C catalysts were significantly affected by doping with the nanosized metal oxides. The chemical structure of 2,2'-dichlorohydrazobenzene was confirmed by H-1 and C-13 NMR spectroscopy. (C) 2008 Elsevier B.V. All rights reserved.