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PPy/AQS (9, 10-anthraquinone-2-sulfonic acid) and PPy/ARS (Alizarin Red's) modified stainless steel mesh as cathode membrane in an integrated MBR/MFC system

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Indexed by: Journal Article

Date of Publication: 2014-09-15

Journal: DESALINATION

Included Journals: Scopus、EI、SCIE

Volume: 349

Page Number: 94-101

ISSN: 0011-9164

Key Words: Stainless steel mesh; Cathode membrane modification; Wastewater treatment; MBR/MFC

Abstract: TO increase effluent quality and membrane flux, membrane bioreactor was integrated with microbial fuel cell (MBR/MFC), in which functional cathode membranes could enable fouling reduction and even electro-catalytic pollutant degradation using the bin-generated electricity. Modifying stainless steel mesh (SSM) with only polypyrrole (PPy) or cheap ARS (Alizarin Red's) or expensive AQS (9,10-anthraquinone-2-sulfonic acid) doped PPy film, helped obtain high ORR (oxygen reduction reaction) activity and higher power output in the integrated MBR/MFC system. The ARS and PPy modified cathode membranes, could not only increase the degradation of (MB) methylene blue (>90%, 1 h), but also enable higher antifouling property infiltrations. Most importantly, replacing the blank SSM, the use of PPy/AQS, PPy/ARS and PPy modified SSM, increased power density 31.37, 27.06 and 23.7 times respectively in the integrated MBR/MFC system. The new system has great application potential and economic feasibility in effective removal of COD and NH4+-N nutrients, has better effluent qualities and has higher energy recovery. (C) 2014 Elsevier B.V. All rights reserved.

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