仲剑初

个人信息Personal Information

副教授

硕士生导师

任职 : 中国无机盐工业协会硼化工分会秘书长, 全国无机盐信息总站硼化物协作组秘书长, 中国化工学会无机酸碱盐专委会硼化物专家组成员, 辽宁省硼镁资源化工与新材料工程技术研究中心副主任, 辽宁省硼镁特种功能材料制备与应用技术工程实验室副主任, 辽宁省非金属矿工业协会副会长.

性别:男

毕业院校:近畿大学

学位:博士

所在单位:化工学院

学科:化学工艺. 功能材料化学与化工

办公地点:大连理工大学西部校区化工综合楼A610

电子邮箱:jczhong@dlut.edu.cn

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Preparation and application of colemanite matrix complex flame retardant

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论文类型:会议论文

发表时间:2015-10-30

收录刊物:EI、Scopus

卷号:852

页面范围:670-676

摘要:In this paper, stearic acid, titanate coupling agent (NDZ-311) and silane coupling agent (KH-570) were selected as modifiers to modify colemanite powder and the resulted products were characterized by XRD and FT-IR. The results show that the surfaces of colemanite particles were effectively modified by stearic acid and coupling agents. The modified colemanite /EVA composites were then prepared and the effect of coupling agent addition on the mechanical properties and flame retardancy of EVA composites was investigated. The EVA composite doped with 40% of modified colemanite (coupling agent accounting for 1% of colemanite mass) exhibits a tensile strength of 9.80MPa, a breaking elongation of 696.5% and a limit oxygen index of 29.6%. The complex flame retardant was obtained by means of grafting amine polyphosphate onto the surface of colemanite using polyphosphoric acid (PPA) and laurylamine as raw materials. The obtained product was analyzed by XRD and FT-IR. The EVA composite doped with 40% of the complex flame retardant has a tensile strength of 8.57MPa, a breaking elongation of 671.3% and a limit oxygen index of 32.6%. ? 2016 Trans Tech Publications, Switzerland.