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Indexed by:期刊论文

Date of Publication:2011-05-01

Journal:ACS CATALYSIS

Included Journals:Scopus、SCIE、EI

Volume:1

Issue:5

Page Number:437-445

ISSN No.:2155-5435

Key Words:TS-1 packing rings; film; contact area; styrene oxidation

Abstract:Titanium silicalite-1 (TS-1)-coated on stainless steel packing rings of complex geometries provided a large interfacial contact area for improving mass transport processes. Zeolite seeds were assembled using organic linker, and a thin uniform layer of TS-1 catalyst was deposited on the surface by hydrothermal regrowth. The chemical, structural, and catalytic properties of the TS-1 layer were examined. An order of magnitude higher styrene conversion rate was obtained from the TS-1-coated substrates compared with powder. The catalyst was sensitive to pretreatment, and heat treatment in nitrogen provided a 30% higher conversion rate than the air-calcined samples. The N(2)-pretreated catalyst displayed lower activity loss and better regenerability.