Hits:
Indexed by:期刊论文
Date of Publication:2014-03-01
Journal:SYNTHESIS-STUTTGART
Included Journals:SCIE、EI、Scopus
Volume:46
Issue:5
Page Number:607-612
ISSN No.:0039-7881
Key Words:fluorine; transition metals; copper; catalysis; radicals
Abstract:A copper/silver-catalyzed decarboxylative trifluoromethylation of alpha,beta-unsaturated carboxylic acids with CF3SO2Na was performed under relatively mild conditions. The reaction shows high E/Z selectivity and wide substrate tolerance. Ag2CO3 plays an important role in promoting the decarboxylation process.
Pre One:Highly efficient Cu(I)-catalyzed trifluoromethylation of aryl(heteroaryl) enol acetates with CF3 radicals derived from CF3SO2Na and TBHP at room temperature
Next One:Mechanistic Understanding on Dinuclear Cobalt(III) Complex Mediated Highly Enantioselective Copolymerization of meso-Epoxides with CO2
