Palladium-Catalyzed Desulfitative Arylation by C-O Bond Cleavage of Aryl Inflates with Sodium Arylsulfinates
Release Time:2019-03-09 Hits:
Indexed by: Journal Article
Date of Publication: 2012-11-16
Journal: JOURNAL OF ORGANIC CHEMISTRY
Included Journals: Scopus、PubMed、EI、SCIE
Volume: 77
Issue: 22
Page Number: 10468-10472
ISSN: 0022-3263
Abstract: An efficient Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates as arylation reagents by C-O bond cleavage of aryl triflates was developed. With only 2 mol % of Pd(OAc)(2) as catalyst and XPhos as ligand, the reaction proceeded well for a range of substrates.