Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-05-18

Journal: JOURNAL OF ORGANIC CHEMISTRY

Included Journals: Scopus、PubMed、EI、SCIE

Volume: 77

Issue: 10

Page Number: 4849-4853

ISSN: 0022-3263

Abstract: A new and efficient method for palladium(II) catalytic desulfitative conjugate addition of arylsulfinic acids with alpha,beta-unsaturated carbonyl compound has been developed. The key reacting intermediates including aryl Pd(II) sulfinic intermediate, aryl Pd(II), and C=O-Pd complexes were captured by ESI-MS/MS, which provide new experimental evidence for the understanding of addition mechanism.