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Unusual partner radical trimer formation in a host complex of cucurbit[8]uril, ruthenium(II) tris-bipyridine linked phenol and methyl viologen

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Indexed by: Journal Article

Date of Publication: 2010-01-01

Journal: CHEMICAL COMMUNICATIONS

Included Journals: SCIE

Volume: 46

Issue: 3

Page Number: 463-465

ISSN: 1359-7345

Abstract: A stable 1 : 1 : 1 inclusion complex of Ru(bpy)(3)-phenol (1), MV2+ and cucurbit[8]uril (CB[8]) is formed in aqueous solution. In the presence of triethanolamine (TEOA), a light-induced formation of unusual partner radical trimer 1-(MV+center dot)(2)-CB[8] has been observed for the first time.

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