A breathing MOF: direct crystallographic observation of the site-selective C(sp(3))-H functionalization
Release Time:2019-03-13 Hits:
Indexed by: Journal Article
Date of Publication: 2016-01-01
Journal: RSC ADVANCES
Included Journals: EI、SCIE
Volume: 6
Issue: 57
Page Number: 51936-51940
ISSN: 2046-2069
Abstract: A 3D breathing MOF was synthesized by hierarchical methods for light-driven acceleration of the site-selective C(sp(3))-H activation. The 1D channels of the assembled MOF can encapsulate the reaction substrates via a breathing process that was observed by single-crystal X-ray analyses. The weak interactions between the encapsulated substrate and the photoactive center facilitated the in situ generation of the active alkyl radicals.
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