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A photosensitizing decatungstate-based MOF as heterogeneous photocatalyst for the selective C-H alkylation of aliphatic nitriles

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Indexed by:Journal Papers

Date of Publication:2016-03-28

Journal:CHEMICAL COMMUNICATIONS

Included Journals:SCIE、PubMed

Volume:52

Issue:25

Page Number:4714-4717

ISSN No.:1359-7345

Abstract:The efficient photosensitizing of decatungstate-based MOF with 1D channels was achieved via in situ synthesis under solvothermal conditions for light driven acceleration of beta- or gamma-site C-H alkylation of aliphatic nitriles. The high catalytic efficiency, excellent size selectivity, high stability and good recyclability of the photocatalyst offer an environmentally-friendly route for widening the scope of accessible nitriles in both laboratory and industry.

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