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Preparation of Amorphous Carbon Nanotubes (a-CNTs) from Vanadium Dioxide@Organic Carbon Core-Shell-structured Composites and Their Thermal Stability in Air

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Indexed by:期刊论文

Date of Publication:2013-12-05

Journal:CHEMISTRY LETTERS

Included Journals:SCIE、Scopus

Volume:42

Issue:12

Page Number:1502-1504

ISSN No.:0366-7022

Abstract:A novel route was developed to synthesize amorphous carbon nanotubes (a-CNTs) from organic carbon using V2O5 and glucose solution as the starting materials. The annealing process can stabilize organic carbon shells, leading to the successful formation of a-CNTs, which is the crucial step for preparing a-CNTs. The as-obtained a-CNTs have uniform diameters with outer diameter ranging from 150 to 250-nm and inner diameter about 30 nm on average, and their length is up to several micrometers. The carbon in the as-synthesized a-CNTs is completely amorphous, and the as-prepared a-CNTs are a kind of hydrogenated a-CNTs containing both sp(3)- and sp(2) carbons. Furthermore, the as-prepared a-CNTs have good thermal stability and oxidation resistance below 305 degrees C in air.

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