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论文类型：期刊论文

发表时间：2017-11-16

发表刊物：CHEMISTRY-AN ASIAN JOURNAL

收录刊物：SCIE、EI、PubMed

卷号：12

期号：22

页面范围：2942-2949

ISSN号：1861-4728

关键字：hollow structures; Kirkendall effect; nanostructures; Ostwald ripening; photochemistry

摘要：Hollow hybrid nanostructures have received significant attention because of their unique structural features. This study reports a facile ion adsorption-heating method to fabricate hollow PbS-TiO2 hybrid particles. In this method, the TiO2 spheres used as a substrate material to grow PbS are aggregates of many small amorphous TiO2 particles, and each small particle is covered with thioglycolic acid ligands through Ti4+-carboxyl coordination. When Pb2+ ions are added to a colloidal solution of these TiO2 spheres, these ions are adsorbed by sulfhydryl (-SH) groups to form metal thiolates, and the C-S bond is dissociated by heating to release S2-. The S2- ions react with Pb2+ ions to form PbS without additive sulfur sources. Additionally, the amorphous TiO2 spheres are transformed into the anatase phase during the heating process. As a result, the crystallization of TiO2 spheres along with the formation of PbS is simultaneously carried out by heating. During the heating process, owing to the Kirkendall effect of S2- diffusion and the Ostwald ripening effect of the crystallization of amorphous TiO2 spheres, PbS-TiO2 hollow hybrid structures can be obtained. The XRD and XPS characterizations proved the formation of anatase TiO2 and PbS. The TEM characterization confirmed the formation of hollow structures in the PbS-TiO2 hybrid sample. The photocatalytic activity of the hollow PbS-TiO2 hybrid spheres have been investigated for the degradation of Cr6+ under visible light. The results show that hollow PbS-TiO2 hybrid spheres exhibited the highest photocatalytic activity, in which almost all the Cr6+ was degraded after 140min.