个人信息Personal Information
教授
博士生导师
硕士生导师
性别:女
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:应用化学. 精细化工. 有机化学
办公地点:大连市高新区凌工路2号西部校区化工楼E434房间
联系方式:0411-84986265
电子邮箱:zhangshf@dlut.edu.cn
Stable diazonium salts of weakly basic amines-Convenient reagents for synthesis of disperse azo dyes
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论文类型:期刊论文
发表时间:2017-01-01
发表刊物:DYES AND PIGMENTS
收录刊物:SCIE、EI
卷号:136
页面范围:63-69
ISSN号:0143-7208
关键字:Stable solid diazonium salts; Weakly basic amines; Disperse azo dyes; Diazotization
摘要:A new synthetic strategy for industrially important deep-shade disperse azo dyes was presented in this study. The key procedure is to prepare stable solid diazonium salts of weakly basic amines in the absence of concentrated sulfuric acid. Diazotization by tert-butyl nitrite in ethyl acetate was allowed to proceed in the presence of equivalent 1,5-naphthalenedisulfonic acid as stabilizer of diazonium salts and donor of hydrogen ion for the reaction. The separated solid diazonium salts exhibited good thermal stability. The corresponding disperse azo dyes were subsequently synthesized through the azo-coupling of the prepared solid diazonium salts with a range of aromatic tertiary amines. The azo dyes were produced in short reaction time, excellent yields, mild reaction conditions, simple experimental procedure and low energy consumption. (C) 2016 Elsevier Ltd. All rights reserved.