张淑芬

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:应用化学. 精细化工. 有机化学

办公地点:大连市高新区凌工路2号西部校区化工楼E434房间

联系方式:0411-84986265

电子邮箱:zhangshf@dlut.edu.cn

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Development and characterization of amphiphilic hydroxyethyl starch derivatives

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论文类型:期刊论文

发表时间:2017-03-04

发表刊物:JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY

收录刊物:SCIE、EI、Scopus

卷号:38

期号:3

页面范围:339-346

ISSN号:0193-2691

关键字:Amphiphilic; foam concrete; hydroxyethyl starch; triazine

摘要:Novel amphiphilic hydroxyethyl starch derivatives 2,4-bistertbutylphenoxy-[1,3,5] -triazine-6-yl)-hydroxyethyl starch with different degrees of substitution of hydrophilic triazine group and hydrophobic hydroxyethyl were prepared by reacting corn starch with chlorohydrin and 2,4-Ditertbutyl phenoxyl-6-chloro-[1,3,5]-triazine, successively. Their structure was characterized by FTIR, H-1 NMR, and SEM. It exhibits ideal surfacial abilities and compressive strength. The surface tension of the amphiphilic hydroxyethyl starch derivatives (MS=1.1, DS=0.026) reached 33.35 mNm(-1) at the critical aggregation concentration (CAC) at 25 degrees C. The compressive strength of foam concrete was 0.97MPa when the amount of added starch derivatives (MS=1.1, DS=0.026) reached 0.1wt% of the total weight.