张淑芬

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:应用化学. 精细化工. 有机化学

办公地点:大连市高新区凌工路2号西部校区化工楼E434房间

联系方式:0411-84986265

电子邮箱:zhangshf@dlut.edu.cn

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Separation of Cd(II) and Ni(II) in a binary mixture through competitive adsorption and acid leaching

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论文类型:期刊论文

发表时间:2015-01-01

发表刊物:RSC ADVANCES

收录刊物:SCIE、EI、Scopus

卷号:5

期号:113

页面范围:92885-92892

ISSN号:2046-2069

摘要:Different heavy metals present simultaneously in aqueous solutions should be separated to promote environmental protection. In this study, the biosorbent, succinylated maize straw, was used to separate and recover Cd(II) and Ni(II) ions from a binary mixture. The effects of various factors, such as contact time, pH, multi-metal isotherms, and adsorbent dose on the simultaneous removal of the two metal ions were investigated; a separation factor was introduced to evaluate this separation behavior. A separation process was proposed on the basis of the competitive adsorption results to separate metal ions from the binary system. This technique was then successfully employed to separate Cd(II) and Ni(II) ions from the simulated leach liquor of spent Ni-Cd batteries. Approximately 90% of the adsorbed Cd(II) ions were recovered, and the resulting solution contained <0.7 wt% of Cd(II) and >99 wt% of Ni(II).