点击次数：

论文类型：期刊论文

发表时间：2011-11-01

发表刊物：MATERIALS CHEMISTRY AND PHYSICS

收录刊物：Scopus、SCIE、EI

卷号：130

期号：3

页面范围：1372-1379

ISSN号：0254-0584

关键字：TiO2/silica aerogel composite; 2-sec-Butyl-4,6-dinitrophenol (DNBP); Photocatalyst; Wastewater treatment; Solar light

摘要：Silica aerogels and TiO2/silica aerogel composite photocatalysts were synthesized by sol-gel technique at ambient pressure using orthosilioate and tetra-n-butyl titanate as precursors, respectively. The prepared composite photocatalysts were characterized by XRD, TEM, BET surface area, FT-IR and UV-vis absorption spectra. The results showed that the TiO2/silica aerogel composite photocatalysts possess high surface area. The addition of silica aerogels inhibited the grain growth and phase transformation of anatase to rutile during calcination. The TiO2/silica aerogel composite sample calcined at 500 degrees C with an optimal silica aerogel content of 7 wt.% afforded the highest photocatalytic activity. The photocatalytic degradation of 2-sec-butyl-4,6-dinitrophenol (DNBP) was investigated by using this novel TiO2/silica aerogel composite photocatalyst under solar light irradiation. The effects of irradiation time, pH, catalyst concentration, temperature and initial DNBP concentration were examined as operational parameters. The optimal operational parameters were found as follows: pH as solution pH 4.82, 8 g L-1 catalyst concentration, 20 degrees C, and 240 min irradiation time. The kinetics of DNBP degradation by TiO2/silica aerogel composite fit well a pseudo-first-order kinetic model. The repeatability of photocatalytic activity was also tested. This study showed the feasible and potential use of TiO2/silica aerogel composite photocatalysts in degradation of toxic organic contaminants. (C) 2011 Elsevier B.V. All rights reserved.