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论文类型：期刊论文

发表时间：2010-10-15

发表刊物：CHEMICAL ENGINEERING JOURNAL

收录刊物：SCIE、EI、Scopus

卷号：164

期号：1

页面范围：115-120

ISSN号：1385-8947

关键字：[Fe(III)-ssal]-Al2O3 catalyst; Photo-Fenton-type reaction; 2,4-Dinitrophenol (DNP); Wastewater treatment; Solar light

摘要：Photoassisted Fenton oxidation of 2,4-dinitrophenol (DNP) was studied in detail using a novel Fe(III)-5-sulfosalicylic acid (ssal) complex loaded Al2O3 as catalyst in the presence of H2O2 and solar light. The effects of different reaction parameters such as initial pH, catalyst loading, H2O2 dosage, initial substrate concentration and temperature on photodegradation were investigated and the optimal operational parameters are reported. The repeatability of photocatalytic activity was also tested. The oxidative degradation of DNP by photo-Fenton-type process in the initiation phase and the fast phase both followed the pseudo-first-order kinetics, and possible reaction mechanisms describing the role of the ligand 5-sulfosalicylic acid and the route of degradation were proposed. The Al2O3-supported [Fe(III)-ssal] complex catalyst was found to be very efficient in the decolorization and COD reduction of real wastewater from DNP manufacturing. Thus, this study showed the feasible and potential uses of the catalytic system in oxidative degradation of various organic contaminants and industrial effluents. (C) 2010 Elsevier B.V. All rights reserved.