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Organic electron-rich N-heterocyclic compound as a chemical bridge: building a Bronsted acidic ionic liquid confined in MIL-101 nanocages

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Indexed by:期刊论文

Date of Publication:2013-06-14

Journal:JOURNAL OF MATERIALS CHEMISTRY A

Included Journals:SCIE、EI、Scopus

Volume:1

Issue:22

Page Number:6530-6534

ISSN No.:2050-7488

Abstract:A novel functionalized MOF material, Bronsted acidic ionic liquid (BAIL) confined inside well-defined MIL-101 nanocages, was developed for the first time based on the tandem post-synthetic strategy. The catalytic performance of BAIL confined in MIL-101 material was evaluated by using the acetalization of benzaldehyde with glycol as a probe reaction. The resulting BAIL/MIL-101 material exhibited superior catalytic performance, which is mainly due to the combination of the advantageous merits of ionic liquid catalyst with the desirable microenvironment in the MIL-101 nanocages.

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