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Palladium-Catalyzed Desulfitative Arylation by C-O Bond Cleavage of Aryl Inflates with Sodium Arylsulfinates

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-11-16

Journal: JOURNAL OF ORGANIC CHEMISTRY

Included Journals: Scopus、PubMed、EI、SCIE

Volume: 77

Issue: 22

Page Number: 10468-10472

ISSN: 0022-3263

Abstract: An efficient Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates as arylation reagents by C-O bond cleavage of aryl triflates was developed. With only 2 mol % of Pd(OAc)(2) as catalyst and XPhos as ligand, the reaction proceeded well for a range of substrates.

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