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Copper-Catalyzed Direct Synthesis of Di- and Triphenylamines: A Dramatic Accelerating Effect of 2-Aminophenols

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2010-12-01

Journal: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Included Journals: Scopus、SCIE

Issue: 36

Page Number: 6967-6973

ISSN: 1434-193X

Key Words: Copper; Amines; Amino alcohols; N,O ligands; Reaction mechanisms

Abstract: Utilizing the dramatic accelerating effect of 2-aminophenols, we developed a copper-catalyzed system for the selective synthesis of di- and triphenylamines. In addition, N- and O-arylation could be achieved in coupling reactions between 2-aminophenol and nitroaryl halides.

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