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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本横滨国立大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工. 有机化学
办公地点：大连市高新区凌工路2号大连理工大学西部新区F-412
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Cu(I)/Ag(I)-mediated decarboxylative trifluoromethylation of arylpropiolic acids with Me3SiCF3 at room temperature
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论文类型：期刊论文
发表时间：2016-07-07
发表刊物：TETRAHEDRON
收录刊物：Scopus、SCIE
卷号：72
期号：27-28
页面范围：3858-3862
ISSN号：0040-4020
关键字：Trifluoromethylation; Decarboxylative coupling reaction; Arylpropiolic acids; Trifluoromethylated acetylenes; Cu(I)/Ag(I)-mediated
摘要：A novel Cu(I)/Ag(I)-mediated decarboxylative trifluoromethylation of arylpropiolic acids with Me3SiCF3 has been developed for the construction of Csp-CF3 bond under mild conditions. This method proceeds smoothly at room temperature and shows a widely functional compatibility, providing a series of corresponding trifluoromethylated acetylenyl-containing aromatics in good yields. (C) 2016 Elsevier Ltd. All rights reserved.