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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本横滨国立大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工. 有机化学
办公地点：大连市高新区凌工路2号大连理工大学西部新区F-412
联系方式：大连市高新区凌工路2号大连理工大学西部新区F-412 邮政编码 116024 电话：0411-84986295 电子信箱：ymli@dlut.edu.cn
电子邮箱：ymli@dlut.edu.cn
A highly efficient and widely functional-group-tolerant catalyst system for copper(I)-catalyzed S-arylation of thiols with aryl halides
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论文类型：期刊论文
发表时间：2009-11-21
发表刊物：TETRAHEDRON
收录刊物：SCIE、Scopus
卷号：65
期号：47
页面范围：9737-9741
ISSN号：0040-4020
摘要：A mild, general, and efficient copper-catalyzed system for C-S bond formation with high chemoselectivity and wide functional group tolerance is developed. With CuBr as catalyst and 1,2,3,4-tetrahydro-8-hydroxy-quinoline as ligand, the S-arylation of thiols with aryl halides performed well, the activated aryl iodides could take place even at room temperature, and the activated aryl bromides and chlorides give the corresponding products with good to excellent yields as well. (C) 2009 Elsevier Ltd. All rights reserved.