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    靳焜

    • 高级工程师      
    • 性别:女
    • 毕业院校:抚顺石油学院
    • 学位:学士
    • 所在单位:化工学院
    • 电子邮箱:jinkun@dlut.edu.cn

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    Nickel-catalyzed C-H direct amination of benzoxazoles with secondary amines

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    论文类型:期刊论文

    第一作者:Li, Yaming

    通讯作者:Li, YM (reprint author), Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China.

    合写作者:Liu, Jin,Xie, Yusheng,Zhang, Rong,Jin, Kun,Wang, Xiuna,Duan, Chunying

    发表时间:2012-05-14

    发表刊物:ORGANIC & BIOMOLECULAR CHEMISTRY

    收录刊物:SCIE、EI、PubMed、Scopus

    卷号:10

    期号:18

    页面范围:3715-3720

    ISSN号:1477-0520

    摘要:In this article, a facile, efficient and practical method for Ni-catalyzed direct C-H amination of benzoxazole with secondary amines has been developed. This procedure requires Ni(OAc)(2)center dot 4H(2)O as catalyst, TBHP as oxidant and acid as the additive. Avariety of substituted benzoxazol-2-amines were synthesized in moderate to good yields.