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    • 高级工程师    
    • 性别:女
    • 毕业院校:抚顺石油学院
    • 学位:学士
    • 所在单位:化工学院
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    A highly efficient and widely functional-group-tolerant catalyst system for copper(I)-catalyzed S-arylation of thiols with aryl halides

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      发布时间:2019-03-09

      论文类型:期刊论文

      发表时间:2009-11-21

      发表刊物:TETRAHEDRON

      收录刊物:Scopus、SCIE

      卷号:65

      期号:47

      页面范围:9737-9741

      ISSN号:0040-4020

      摘要:A mild, general, and efficient copper-catalyzed system for C-S bond formation with high chemoselectivity and wide functional group tolerance is developed. With CuBr as catalyst and 1,2,3,4-tetrahydro-8-hydroxy-quinoline as ligand, the S-arylation of thiols with aryl halides performed well, the activated aryl iodides could take place even at room temperature, and the activated aryl bromides and chlorides give the corresponding products with good to excellent yields as well. (C) 2009 Elsevier Ltd. All rights reserved.