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论文类型：期刊论文

发表时间：2014-01-01

发表刊物：RSC ADVANCES

收录刊物：SCIE、EI、Scopus

卷号：4

期号：2

页面范围：624-628

ISSN号：2046-2069

摘要：Solar energy is ideal for photocatalytic degradation of pollutants. For efficient utilization of solar energy, the development of a high-activity and low-cost visible light driven photocatalyst is desired. Here we report a new type of atomic single layer graphitic-C3N4 (SL g-C3N4) as a high-performance photocatalyst for pollutant degradation under visible light (lambda > 400 nm) irradiation. This SL g-C3N4 with thickness of 0.4-0.5 nm was prepared by an ultrasonic exfoliating process employing few layer graphitic-C3N4 nanosheets (g-C3N4 NS) as precursors. As a result of this atomic single layer, prolonged photogenerated charge lifetime and improved charge transfer capability were confirmed by time-resolved fluorescence emission spectra and electrochemical measurements, respectively. During the photocatalytic process under visible light irradiation, the degradation rate of rhodamine B on SL g-C3N4 was about 3.0 and 10.2 times higher than that of the few layer g-C3N4 NS and the bulk g-C3N4, respectively. This high photocatalytic performance is attributed to the atomic single layer structure of SL g-C3N4, which lengthens the lifetime of photogenerated charges and serves as an excellent electron transporter. The excellent performance achieved in this work suggests very appealing applications of SL g-C3N4 in many areas, such as photocatalytic degradation of environmental pollutants, solar cell, photocatalytic water splitting and electronic nanodevices.