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论文类型：期刊论文

发表时间：2010-08-01

发表刊物：ENVIRONMENTAL SCIENCE & TECHNOLOGY

收录刊物：SCIE、EI、PubMed、PKU、ISTIC、Scopus

卷号：44

期号：15

页面范围：5812-5817

ISSN号：0013-936X

摘要：To elucidate the relationship between photochemical functions with the structure of humic acids (HA), we developed a molecular imprinting method to separate the substances with given structure and investigated their photochemical behavior in aqueous solution. The substances with porphyrin-like core structure, such as chlorophyll or heme, were employed as template substances for preparing molecular imprinting polymers (MIP). The polymers were used to separate the substances with porphyrin-like structure from HA. Photochemical experiments were conducted to evaluate effects of the separated HA fractions on the photodegradalion of coexisting organic pollutant The results showed that all fractions bound by MIP accelerated photochemical degradation of coexisting 2,4-dichlorophenoxyacetic acid (2,4-D) under simulated sunlight (lambda > 290 nm) irradiation, indicating that HA with porphyrin-like structure possesses better photoactivity than ones without the structure. The photochemical degradation of 2,4-D was enhanced when Fe(III), the ubiquitous element in natural aquatic systems, was added owing to the formation of Fe(III) complex with the HA. Electron paramagnetic resonance (EH) spectra indicated that OH(center dot) and (1)O(2) radicals were generated in the solutions of HA fractions bound by MIP under simulated sunlight irradiation, implying that 2,4-D degradation could be related to oxidation reactions caused by reactive oxygen species (ROS).