New framework iodoargentates: M(en)(3)Ag2I4 (M = Zn, Ni) with tridymite topology
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论文类型：期刊论文
发表时间：2008-05-19
发表刊物：INORGANIC CHEMISTRY
收录刊物：SCIE、PubMed
卷号：47
期号：10
页面范围：3922-3924
ISSN号：0020-1669
摘要：Two novel framework compounds, Zn(en)(3)Ag2I4 (1) and Ni(en)(3)Ag2I4 (2), have been synthesized by a self-assembly reaction. Both of them contain an unexpected framework, Ag2I42- with tridymite topolopy, and the discrete M(en)(3)(2+) cations are located in the channels. Their thermal properties and circular dichroism spectra were investigated.