王新平
开通时间:..
最后更新时间:..
点击次数:
论文类型:期刊论文
发表时间:2012-09-01
发表刊物:MICROPOROUS AND MESOPOROUS MATERIALS
收录刊物:SCIE、EI、Scopus
卷号:159
页面范围:105-110
ISSN号:1387-1811
关键字:SUZ-4 zeolite; Nanofiber; Seed slurry
摘要:Uniform SUZ-4 zeolite nanofiber (about 12 x 1500 nm) was obtained for the first time. The SUZ-4 zeolite was synthesized by hydrothermal treatment of the initial aluminosilicate gel at 150 degrees C with the assistance of definite amount of special seed slurry while without additional use of template. It was found that morphology of the SUZ-4 zeolite synthesized can be simply controlled by the character of seed slurry that is mainly determined by the crystallization period in preparation. The seed slurry containing plenty of less stable SUZ-4 crystallites obtained by crystallizing the aluminosilicate gel (7.9 KOH:1.0 Al2O3:2.6 TEA-OH:21.2 SiO2:498.6 H2O) under rotation at 150 degrees C for 16h leads to the synthesis of nanofibrous SUZ-4. while that primarily containing stable SUZ-4 crystallites obtained by prolonged crystallization period leads to the synthesis of rod-like zeolite. (C) 2012 Elsevier Inc. All rights reserved.