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Indexed by:期刊论文

Date of Publication:2014-06-01

Journal:INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals:SCIE、Scopus

Volume:44

Page Number:169-172

ISSN No.:1387-7003

Key Words:Hydrothermal synthesis; Indium sulfide; Template effect; Crystal structure

Abstract:Two indium sulfides [(Me)(4)N](6)[In10S18] (1) and [(Me)(4)N](13)[Cu5In30S54] (2) have been hydrothermally synthesized. Compound 1 is a 3D open framework built from T3 clusters, which has large porosity. Compound 2 has a double-layered structure constructed by T5 clusters. Our results indicate that tetramethylammonium ion is an efficient structure-directing agent for both ternary and quaternary indium sulfides. The optical and thermal properties have also been investigated. (C) 2014 Elsevier B.V. All rights reserved.