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Hydrothermal syntheses and characterization of two tetramethylammonium templated indium sulfides

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2014-06-01

Journal: INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals: Scopus、SCIE

Volume: 44

Page Number: 169-172

ISSN: 1387-7003

Key Words: Hydrothermal synthesis; Indium sulfide; Template effect; Crystal structure

Abstract: Two indium sulfides [(Me)(4)N](6)[In10S18] (1) and [(Me)(4)N](13)[Cu5In30S54] (2) have been hydrothermally synthesized. Compound 1 is a 3D open framework built from T3 clusters, which has large porosity. Compound 2 has a double-layered structure constructed by T5 clusters. Our results indicate that tetramethylammonium ion is an efficient structure-directing agent for both ternary and quaternary indium sulfides. The optical and thermal properties have also been investigated. (C) 2014 Elsevier B.V. All rights reserved.

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