Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2013-06-14

Journal: JOURNAL OF MATERIALS CHEMISTRY A

Included Journals: Scopus、EI、SCIE

Volume: 1

Issue: 22

Page Number: 6530-6534

ISSN: 2050-7488

Abstract: A novel functionalized MOF material, Bronsted acidic ionic liquid (BAIL) confined inside well-defined MIL-101 nanocages, was developed for the first time based on the tandem post-synthetic strategy. The catalytic performance of BAIL confined in MIL-101 material was evaluated by using the acetalization of benzaldehyde with glycol as a probe reaction. The resulting BAIL/MIL-101 material exhibited superior catalytic performance, which is mainly due to the combination of the advantageous merits of ionic liquid catalyst with the desirable microenvironment in the MIL-101 nanocages.