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New framework iodoargentates: M(en)(3)Ag2I4 (M = Zn, Ni) with tridymite topology

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Indexed by: Journal Article

Date of Publication: 2008-05-19

Journal: INORGANIC CHEMISTRY

Included Journals: SCIE、PubMed

Volume: 47

Issue: 10

Page Number: 3922-3924

ISSN: 0020-1669

Abstract: Two novel framework compounds, Zn(en)(3)Ag2I4 (1) and Ni(en)(3)Ag2I4 (2), have been synthesized by a self-assembly reaction. Both of them contain an unexpected framework, Ag2I42- with tridymite topolopy, and the discrete M(en)(3)(2+) cations are located in the channels. Their thermal properties and circular dichroism spectra were investigated.

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