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New framework iodoargentates: M(en)(3)Ag2I4 (M = Zn, Ni) with tridymite topology

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Indexed by:期刊论文

Date of Publication:2008-05-19

Journal:INORGANIC CHEMISTRY

Included Journals:PubMed、SCIE

Volume:47

Issue:10

Page Number:3922-3924

ISSN No.:0020-1669

Abstract:Two novel framework compounds, Zn(en)(3)Ag2I4 (1) and Ni(en)(3)Ag2I4 (2), have been synthesized by a self-assembly reaction. Both of them contain an unexpected framework, Ag2I42- with tridymite topolopy, and the discrete M(en)(3)(2+) cations are located in the channels. Their thermal properties and circular dichroism spectra were investigated.

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