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发布时间：2019-03-20

论文类型：期刊论文

发表时间：2018-01-01

发表刊物：Chinese journal of structural Chemistry

卷号：37

期号：12

页面范围：1979-1986

摘要：One two-dimensional compound (PyH)[Cu2(ttc)] (PyH = protonated pyridine) was solvothermally synthesized in the presence of thiophenol mineralizer using ttcH3 (1,3,5-triazine-2,4,6-trithione, trithiocyanuric acid) ligand. It crystallizes in the triclinic system, space group P1 with a = 7.6824(12), b = 7.8094(13), c = 9.9541(18) Å, V = 555.95(16) Å3, Z = 2, T = 296(2) K, GOOF = 1.136, λ(MoKα) = 0.71073 Å, Dc = 4.555 g/cm3, Cu2S3N4C8H6, Mr = 382, F(000) = 737, the final R = 0.0654, wR = 0.1936 for 1558 observed reflections with I ＞ 2(I). Structure analyses indicate that the whole Cu(I) atoms have planar triangular coordination. The compound shows intense fluorescent emission and high thermal stability. © 2018 Fujian Institute of Research of the Structure of Matter. All Rights Reserved.