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论文类型:期刊论文
第一作者:Zhang, Chi
通讯作者:An, YL (reprint author), Dalian Univ Technol, Sch Chem, Dalian 116024, Peoples R China.
合写作者:Liu, Jinming,Ji, Min,An, Yonglin
发表时间:2014-06-01
发表刊物:INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物:SCIE、Scopus
卷号:44
页面范围:169-172
ISSN号:1387-7003
关键字:Hydrothermal synthesis; Indium sulfide; Template effect; Crystal structure
摘要:Two indium sulfides [(Me)(4)N](6)[In10S18] (1) and [(Me)(4)N](13)[Cu5In30S54] (2) have been hydrothermally synthesized. Compound 1 is a 3D open framework built from T3 clusters, which has large porosity. Compound 2 has a double-layered structure constructed by T5 clusters. Our results indicate that tetramethylammonium ion is an efficient structure-directing agent for both ternary and quaternary indium sulfides. The optical and thermal properties have also been investigated. (C) 2014 Elsevier B.V. All rights reserved.