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论文类型：期刊论文

第一作者：Ji, Min

通讯作者：Ji, M (reprint author), Dalian Univ Technol, Sch Chem, Dalian 116023, Peoples R China.

合写作者：Zhang, Xiaoyan,Wang, Junhu,Park, Sang-Eon

发表时间：2013-05-01

发表刊物：JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

收录刊物：SCIE、EI

卷号：371

页面范围：36-41

ISSN号：1381-1169

关键字：Ethylbenzene dehydrogenation; Spinel; Fe-57 Mossbauer spectroscopy; Synergy

摘要：Fe-doped MgAl2O4 spinet catalyst of MgFe0.1Al1.9O4 and supported catalyst of Fe2O3-MgO/gamma-Al2O3 for ethylbenzene dehydrogenation in the presence of CO2 were studied by Mossbauer spectroscopy (MS) combining with the partial reduction method in the presence of H-2, and the catalytic activity of the ferrous iron species was discussed. The results showed that the catalytic performance of Fe3+ existing in spinel is superior to alpha-Fe2O3, and the synergistic effect between Fe2+ and Fe3+ might indeed increase the catalytic activity since Fe2+-O2- formed in the process of reduction has moderate basicity, which was more favorable for desorption of CO2 compared with Mg2+-O2-. The reduced MgFe0.1Al1.9O4 containing Fe2+ of around 25% exhibits much higher catalytic activity than unreduced catalyst, with improved styrene yield nearly 2 times to 45.0%. MgxFe1-xO as another ferrous iron species formed in the reduction process of Fe2O3-MgO/gamma-Al2O3 showed inconspicuously catalytic activity. (C) 2013 Elsevier B.V. All rights reserved.