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论文类型：期刊论文

第一作者：Yao, Hua-Gang

通讯作者：An, YL (reprint author), Dalian Univ Technol, Dept Chem, Dalian 116024, Peoples R China.

合写作者：Zhou, Peng,Ji, Shou-Hua,Ji, Min,An, Yong-Lin,Ning, Gui-ling

发表时间：2009-01-01

发表刊物：ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

收录刊物：SCIE、Scopus

卷号：635

期号：13-14

页面范围：2328-2332

ISSN号：0044-2313

关键字：Chain compounds; Copper; Hydrothermal synthesis; N ligands; Reduction

摘要：Copper(I) complexes, [Cu(2)Cl(2)(phen)](infinity) (1; phen = 1, 10-phenanthroline), [Cu(2)(SCN)(CN)(phen)(2)](infinity) (2), and [Cu(SCN)(bipy)](infinity) (3; bipy = 2,2'-bipyridine) were synthesized by hydrothermal reduction with tartaric acid as reducing reagent. Compound 1 exhibits mu(2)-Cl and mu(3)-Cl modes that construct unique Cu(3)Cl(3) six-membered ring units, which form a one-dimensional infinite chain structure by sharing common edges. Alternating CN(-) and SCN(-) ligands bridge Cu atoms to form an infinite helical chain in compound 2. Compound 3 consists of an infinite split-stair chain formed by [Cu(bipy)](+) unit joined by SCN- groups. The IR spectra and luminescence and thermal properties of 1 and 3 were investigated at room temperature in the solid state.