大连理工大学主页平台管理系统赵艳秋 A new sensor for detection of CH3CN and ClCH2CN vapors based on vapoluminescent platinum(II) complex 中文主页

论文成果

A new sensor for detection of CH3CN and ClCH2CN vapors based on vapoluminescent platinum(II) complex: 点击次数：; 发布时间： 2019-03-09; 发布时间：2019-03-09; 论文类型：期刊论文; 发表时间：2013-09-28; 发表刊物：DALTON TRANSACTIONS; 收录刊物：Scopus、EI、SCIE、PubMed; 卷号：42; 期号：36; 页面范围：13092-13100; ISSN号：1477-9226; 摘要：The planar platinum(II) complex [Pt(Me3SiC CbpyC CSiMe3)(C CC6H4Et-4)(2)] (1) with 5,5-bis(trimethylsilylethynyl)-2,2'-bipyridine was prepared and characterized. Solid-state 1 exhibits unusual, selective and reversible luminescence vapochromism to CH3CN and ClCH2CN vapors, which is useful for the detection of these hazardous vapors. A vapochromic cycle was monitored by dynamic variations in emission spectra and X-ray diffraction (XRD) patterns. Both X-ray crystallographic and density functional theory studies suggest that the vapochromic and vapoluminescent behavior of 1 are induced by the variation in the intermolecular Pt-Pt interactions.

上一条： Thermo- and mechanical-grinding-triggered color and luminescence switches of the diimine-platinum(II) complex with 4-bromo-2,2'-bipyridine

下一条：可见光-近红外发光开关材料的研究

副教授硕士生导师

性别：女

毕业院校：大连理工大学

学位：硕士

所在单位：化学学院

学科：有机化学

办公地点：西部校区化工综合楼 C303

电子邮箱：