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1-Dibenzylamino-1-deoxy-4,5-O-isopropylidene-beta-D-fructopyranose

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2011-02-01

Journal: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Included Journals: PubMed、SCIE、Scopus

Volume: 67

Issue: Pt 2

Page Number: O387-U830

ISSN: 1600-5368

Abstract: The title compound C23H29NO5, synthesized by the Amadori rearrangement of alpha-D-glucose with dibenzylamine and the ketalization, is shown to be a beta-anomer. The fructopyranose ring adopts a chair conformation. The two benzene rings form a dihedral angle of 68.9 (1)degrees. In the crystal, non-classical intermolecular C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network.

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