|
个人信息Personal Information
教授
博士生导师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：高分子材料. 高分子化学与物理. 功能材料化学与化工
办公地点：大连理工大学西部校区化工实验楼A405
联系方式：手机：13009436945
电子邮箱：wangjinyan@dlut.edu.cn
Inherent N,O-containing carbon frameworks as electrode materials for high-performance supercapacitors
点击次数：
论文类型：期刊论文
发表时间：2016-09-28
发表刊物：NANOSCALE
收录刊物：SCIE、EI、PubMed、Scopus
卷号：8
期号：36
页面范围：16323-16331
ISSN号：2040-3364
摘要：N,O-Containing micropore-dominated materials have been developed successfully via temperature-dependent cross-linking of 4,4'-(dioxo-diphenyl-2,3,6,7-tetraazaanthracenediyl)dibenzonitrile (DPDN) monomers. By employing a molecular engineering strategy, we have designed and synthesized a series of porous heteroatom-containing carbon frameworks (PHCFs), in which nitrogen and oxygen heteroatoms are distributed homogeneously throughout the whole framework at the atomic level, which can ensure the stability of its electrical properties. The as-made PHCFs@550 exhibits a high specific capacitance of 378 F g(-1), with an excellent long cycling life, including excellent cycling stability (capacitance retention of ca. 120% over 20 000 cycles). Moreover, the successful preparation of PHCFs provides new insights for the fabrication of nitrogen and oxygen-containing electrode materials from readily available components via a facile route.