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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：高分子材料. 高分子化学与物理. 功能材料化学与化工
办公地点：大连理工大学西部校区化工实验楼A405
联系方式：手机：13009436945
电子邮箱：wangjinyan@dlut.edu.cn
Efficient oxidation of cyclohexene over tetrakis(diperoxomolybdo) phosphate immobilized on poly(phthalazinone ether sulfone ketone) with hydrogen peroxide
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论文类型：期刊论文
发表时间：2008-05-01
发表刊物：APPLIED CATALYSIS A-GENERAL
收录刊物：SCIE、EI
卷号：339
期号：2
页面范围：145-150
ISSN号：0926-860X
关键字：heteropoly anion; poly(phthalazinone ether sulfone ketone); polymer-supported; cyclohexene; hydrogen peroxide
摘要：Heteropoly anion [PMo4O24](3-) (PMo) was immobilized on the quaternary-ammonium poly(phthalazinone ether sulfone ketone) (QAPPESK) support by taking advantage of the overall negative charge of anion. The supported catalyst QAPPESK-PMo was fully characterized by FT-IR and XRD. The results of analyses indicated that the PMos were finely dispersed on the polymer support via chemical interactions. This supported catalyst was employed to catalyze oxidation of olefins with hydrogen peroxide, and satisfying results were obtained under mild heterogeneous conditions. The effects of various reaction factors, such as solvent, the amount of H2O2 and catalyst used, were studied. Furthermore, the leaching and recycling tests revealed that the supported catalyst was highly efficient and robust. (c) 2008 Elsevier B.V. All rights reserved.