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Copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with CF3CO2Na and elemental sulfur

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Indexed by:期刊论文

Date of Publication:2013-12-02

Journal:TETRAHEDRON

Included Journals:SCIE、Scopus

Volume:69

Issue:48

Page Number:10262-10266

ISSN No.:0040-4020

Key Words:Copper-mediated; Oxidation; Trifluoromethylthiolation; Sodium trifluoroacetate; Synthetic methods

Abstract:A practical three-component copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with cheap and readily available sodium trifluoroacetate and elemental sulfur is reported. A variety of trifluoromethylthio-substituted aromatics are synthesized in moderate yields under mild reaction conditions. (C) 2013 Elsevier Ltd. All rights reserved.

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