Copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with CF3CO2Na and elemental sulfur
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论文类型：期刊论文
发表时间：2013-12-02
发表刊物：TETRAHEDRON
收录刊物：Scopus、SCIE
卷号：69
期号：48
页面范围：10262-10266
ISSN号：0040-4020
关键字：Copper-mediated; Oxidation; Trifluoromethylthiolation; Sodium trifluoroacetate; Synthetic methods
摘要：A practical three-component copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with cheap and readily available sodium trifluoroacetate and elemental sulfur is reported. A variety of trifluoromethylthio-substituted aromatics are synthesized in moderate yields under mild reaction conditions. (C) 2013 Elsevier Ltd. All rights reserved.