Palladium-Catalyzed Desulfitative Arylation by C-O Bond Cleavage of Aryl Inflates with Sodium Arylsulfinates
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论文类型：期刊论文
发表时间：2012-11-16
发表刊物：JOURNAL OF ORGANIC CHEMISTRY
收录刊物：Scopus、PubMed、EI、SCIE
卷号：77
期号：22
页面范围：10468-10472
ISSN号：0022-3263
摘要：An efficient Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates as arylation reagents by C-O bond cleavage of aryl triflates was developed. With only 2 mol % of Pd(OAc)(2) as catalyst and XPhos as ligand, the reaction proceeded well for a range of substrates.