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个人信息Personal Information
高级工程师
性别：女
毕业院校：青岛海洋大学
学位：硕士
所在单位：化工学院
电子邮箱：fuxinmei@dlut.edu.cn
扫描关注
A highly efficient and widely functional-group-tolerant catalyst system for copper(I)-catalyzed S-arylation of thiols with aryl halides
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论文类型：期刊论文
发表时间：2009-11-21
发表刊物：TETRAHEDRON
收录刊物：SCIE、Scopus
卷号：65
期号：47
页面范围：9737-9741
ISSN号：0040-4020
摘要：A mild, general, and efficient copper-catalyzed system for C-S bond formation with high chemoselectivity and wide functional group tolerance is developed. With CuBr as catalyst and 1,2,3,4-tetrahydro-8-hydroxy-quinoline as ligand, the S-arylation of thiols with aryl halides performed well, the activated aryl iodides could take place even at room temperature, and the activated aryl bromides and chlorides give the corresponding products with good to excellent yields as well. (C) 2009 Elsevier Ltd. All rights reserved.