Release Time:2019-03-12  Hits:

Indexed by: Journal Article

Date of Publication: 2018-09-12

Journal: ACS APPLIED MATERIALS & INTERFACES

Included Journals: SCIE、PubMed

Volume: 10

Issue: 36

Page Number: 30409-30416

ISSN: 1944-8244

Key Words: copper redox mediator; dye-sensitized solar cells; ligand engineering; stability; energy conversion

Abstract: The identification of an efficient and stable redox mediator is of paramount importance for commercialization of dye-sensitized solar cells (DSCs). Herein, we report a new class of copper complexes containing diamine-dipyridine tetradentate ligands (L1 = N,N'-dibenzyl-N,N'-bis-(pyridin-2-ylmethyl)ethylenediamine; L2 = N,N'-dibenzyl-N,N'-bis (6-methyl-pyridin-2-ylmethyl)ethylenediamine) as redox mediators in DSCs. Devices constructed with [Cu(L2)](2+/+) redox couple afford an impressive power conversion efficiency (PCE) of 9.2% measured under simulated one sun irradiation (100 mW cm(-2), AM 1.5G), which is among the top efficiencies reported thus far for DSCs with copper complex-based redox mediators. Remarkably, the excellent air, photo, and electrochemical stability of the [Cu(L2)](2+/+) complexes renders an outstanding long-term stability of the whole DSC device, maintaining similar to 90% of the initial efficiency over 500 h under continuous full sun irradiation. This work unfolds a new platform for developing highly efficient and stable redox mediators for large-scale application of DSCs.